Linear combination of eigenstates of L2 and Lz
Task number: 4580
The particles are in a state \(|\psi\rangle\), which is a linear combination of the common eigenstates of \(\hat L^2\) and \(\hat L_z\) with quantum numbers \(l = 1\) and \(m = 0, \, \pm1\), i.e.,
\[ |\psi\rangle = a \, |1, \, 1\rangle + b \, |1, \, 0\rangle + c \, |1, \, -1\rangle \, . \]Calculate
a) the expectation values of the components of the angular momentum,
b) the expectation values of the squares of the components of the angular momentum.
c) The particles in the state \(|\psi\rangle\) pass through a Stern–Gerlach apparatus aligned along the \(z\)‑axis and split into three beams. The beam of particles with \(L_z = \hbar\) is then directed into a second apparatus aligned along the \(x\)‑axis. What values of \(L_x\) will be measured, and with what probabilities?
Hint 1
Recall or look up the relation for calculating the expectation value of a physical observable \(F\) in a state described by the normalised wavefunction \(\psi\).
Hint 2
Recall or look up the form of the basis states \(|1, \, m\rangle\) in the matrix representation, as well as the form of the angular momentum component operators expressed in this basis.
Solution a)
First, we express the state \(|\psi\rangle\) in the matrix representation (see Hint 2)
\[ |\psi\rangle = a |1, \, 1\rangle + b |1, \, 0\rangle + c |1, \, -1\rangle = \] \[ = a \begin{pmatrix} 1 \\ 0 \\ 0 \end{pmatrix} + b \begin{pmatrix} 0 \\ 1 \\ 0 \end{pmatrix} + c \begin{pmatrix} 0 \\ 0 \\ 1 \end{pmatrix} = \begin{pmatrix} a \\ b \\ c \end{pmatrix} \, . \]To compute the expectation value, we use the general formula, substitute the matrix representation, and simplify
\[ \langle L_x \rangle_\psi = \left \langle \psi \, \Big | \, \hat L_x \psi \right \rangle = \psi^\dagger \hat L_x \psi = \begin{pmatrix} a^* & b^* & c^* \end{pmatrix} \frac{\hbar}{\sqrt2} \begin{pmatrix} 0 & 1 & 0 \\ 1 & 0 & 1 \\ 0 & 1 & 0 \end{pmatrix} \begin{pmatrix} a \\ b \\ c \end{pmatrix} = \] \[ = \frac{\hbar}{\sqrt2} \begin{pmatrix} a^* & b^* & c^* \end{pmatrix} \begin{pmatrix} b \\ a+c \\ b \end{pmatrix} = \frac{\hbar}{\sqrt2} (a^*b + ab^* + b^*c + bc^*) \, . \]Note: Since this is the expectation value of a physical observable, the expression in parentheses must be real. Indeed, it is, because
\[ a^*b + ab^* + b^*c + bc^* = 2 \, \mathrm{Re} (ab^*) + 2 \, \mathrm{Re} (bc^*) \, . \]The calculation for \(\langle L_y \rangle_\psi\) and \(\langle L_z \rangle_\psi\) is completely analogous. The resulting values are
\[ \langle L_y \rangle_\psi = \frac{i\hbar}{\sqrt2} (a{b^*} - {a^*}b + b{c^*} - {b^*}c) \, , \] \[ \langle L_z \rangle_\psi = \hbar^2 (|a|^2 + |c|^2) \, . \]These expectation values are also real. For \(\langle L_z \rangle_\psi\) this is obvious, and for \(\langle L_y \rangle_\psi\) we can rewrite the term in the parentheses as
\[ a{b^*} - {a^*}b + b{c^*} - {b^*}c = 2 i \, \mathrm{Im}(a{b^*}) + 2 i \, \mathrm{Im}(b{c^*}) \, . \]Multiplying this by the \(i\) from the numerator of the fraction in front of the parentheses gives a real expression.
Solution b)
Here we proceed similarly to the previous section, with the difference that we first compute the squares of the angular momentum operators for each component
\[ \hat L_x^2 = \frac{\hbar}{\sqrt2} \begin{pmatrix} 0 & 1 & 0 \\ 1 & 0 & 1 \\ 0 & 1 & 0 \end{pmatrix} \frac{\hbar}{\sqrt2} \begin{pmatrix} 0 & 1 & 0 \\ 1 & 0 & 1 \\ 0 & 1 & 0 \end{pmatrix} = \frac{\hbar^2}{2} \begin{pmatrix} 1 & 0 & 1 \\ 0 & 2 & 0 \\ 1 & 0 & 1 \end{pmatrix} \, , \] \[ \hat L_y^2 = \frac{\hbar}{\sqrt2} \begin{pmatrix} 0 & -i & 0 \\ i & 0 & -i \\ 0 & i & 0 \end{pmatrix} \frac{\hbar}{\sqrt2} \begin{pmatrix} 0 & -i & 0 \\ i & 0 & -i \\ 0 & i & 0 \end{pmatrix} = \frac{\hbar^2}{2} \begin{pmatrix} 1 & 0 & -1 \\ 0 & 2 & 0 \\ -1 & 0 & 1 \end{pmatrix} \, , \] \[ \hat L_z^2 = \hbar \begin{pmatrix} 1 & 0 & 0 \\ 0 & 0 & 0 \\ 0 & 0 & -1 \end{pmatrix} \hbar \begin{pmatrix} 1 & 0 & 0 \\ 0 & 0 & 0 \\ 0 & 0 & -1 \end{pmatrix} = \hbar^2 \begin{pmatrix} 1 & 0 & 0 \\ 0 & 0 & 0 \\ 0 & 0 & 1 \end{pmatrix} \, . \]Next, we substitute into the general formula for the expectation value in the “matrix” representation and simplify
\[ \langle L_x^2 \rangle_\psi = \left \langle \psi \, \Big | \, \hat L_x^2 \psi \right \rangle = \psi^\dagger \hat L_x^2 \psi = \begin{pmatrix} a^* & b^* & c^* \end{pmatrix} \frac{\hbar^2}{2} \begin{pmatrix} 1 & 0 & 1 \\ 0 & 2 & 0 \\ 1 & 0 & 1 \end{pmatrix} \begin{pmatrix} a \\ b \\ c \end{pmatrix} = \] \[ = \frac{\hbar^2}{2} \begin{pmatrix} a^* & b^* & c^* \end{pmatrix} \begin{pmatrix} a+c \\ 2b \\ a+c \end{pmatrix} = \frac{\hbar^2}{2} (aa^* + a^*c + 2bb^* + ac^* + cc^*) = \] \[ = \frac{\hbar^2}{2} (|a|^2 + 2|b|^2 + |c|^2 + {a^*}c + a{c^*}) \, . \]The calculations for \(\langle L_y^2 \rangle_\psi\) and \(\langle L_z^2 \rangle_\psi\) are completely analogous. The results are
\[ \langle L_y^2 \rangle_\psi = \frac{\hbar^2}{2} (|a|^2 + 2|b|^2 + |c|^2 - {a^*}c - a{c^*}) \, , \] \[ \langle L_z^2 \rangle_\psi = \hbar^2 (|a|^2 + |c|^2) \, . \]In all three cases, we obtain real values as expected.
Note: Summing the expectation values of the squares of the individual angular momentum components gives
\[ \langle L^2 \rangle_\psi = \langle L_x^2 \rangle_\psi + \langle L_y^2 \rangle_\psi + \langle L_z^2 \rangle_\psi = 2 \hbar^2 (|a|^2 + |b|^2 + |c|^2) = 2\hbar^2 \, , \]which is consistent with the fact that this is a state with a sharp value of \(\hat L^2\) for \(l = 1\).
Hint 3
Recall or look up how the eigenvalues and eigenvectors of matrices are determined.
Hint 4
Recall or look up how to decompose the state entering the measurement, and how the probabilities of obtaining the individual measurement outcomes can be determined from this decomposition.
Solution c)
After passing through the first Stern–Gerlach apparatus, we select only the particles with the value \(L_z = \hbar\), which corresponds to particles in the state \(|1, \, 1\rangle\). The beam of particles in this state then passes through a Stern–Gerlach apparatus oriented along the \(x\)‑axis. The measurement axiom states that, if we want to determine the probabilities of measuring each of the three possible values, we must express the state entering the measurement as a linear combination of the eigenstates of \(L_x\).
Answer
a) The expectation values of the components of the angular momentum in the state \(|\psi\rangle\) are
\[ \left \langle L_x \right \rangle = \frac{\hbar}{\sqrt2} (a^*b + ab^* + b^*c + bc^*) \, , \] \[ \left \langle L_y \right \rangle = \frac{i\hbar}{\sqrt2} (ab^* - a^*b + bc^* - b^*c) \, , \] \[ \left \langle L_z \right \rangle = \hbar^2 (|a|^2 + |c|^2) \, . \]b) The expectation values of the squares of the components of the angular momentum in the state \(|\psi\rangle\) are
\[ \left \langle L_x^2 \right \rangle = \frac{\hbar^2}{2} (|a|^2 + 2|b|^2 + |c|^2 + {a^*}c + a{c^*}) \, , \] \[ \left \langle L_y^2 \right \rangle = \frac{\hbar^2}{2} (|a|^2 + 2|b|^2 + |c|^2 - {a^*}c - a{c^*}) \, , \] \[ \left \langle L_z^2 \right \rangle = \hbar^2 (|a|^2 + |c|^2) \, . \]c) After the beam of particles with projection \(L_z = \hbar\) passes through a Stern–Gerlach apparatus oriented along the \(x\)‑axis, the values of \(L_x\) are measured with the following probabilities
\[ L_x = +\hbar \, \, \rightarrow \, \, P_{+\hbar} = \frac{1}{4} \, , \] \[ L_x = 0 \, \, \rightarrow \, \, P_0 = \frac{1}{2} \, , \] \[ L_x = -\hbar \, \, \rightarrow \, \, P_{-\hbar} = \frac{1}{4} \, . \]Comment – calculation of the other eigenvectors
Now we determine the eigenvector \(\vec v\) corresponding to the eigenvalue \(\lambda = 0\) by substituting into the equation \(\left ( \hat L_x - \lambda \hat{\mathbb{E}} \right ) \cdot \vec v = \vec o\) and performing the following simplification
\[ \left ( \hat L_x - \lambda \hat{\mathbb{E}} \right ) \cdot \vec v = \left ( \frac{\hbar}{\sqrt2} \begin{pmatrix} 0 & 1 & 0 \\ 1 & 0 & 1 \\ 0 & 1 & 0 \end{pmatrix} - 0 \cdot \begin{pmatrix} 1 & 0 & 0 \\ 0 & 1 & 0 \\ 0 & 0 & 1 \end{pmatrix} \right ) \begin{pmatrix} v_1 \\ v_2 \\ v_3 \end{pmatrix} = \] \[ = \frac{\hbar}{\sqrt2} \begin{pmatrix} 0 & 1 & 0 \\ 1 & 0 & 1 \\ 0 & 1 & 0 \end{pmatrix} \begin{pmatrix} v_1 \\ v_2 \\ v_3 \end{pmatrix} = \begin{pmatrix} 0 \\ 0 \\ 0 \end{pmatrix} \, . \]We divide this equality by the factor \(\frac{\hbar}{\sqrt2}\) and expand it into its component equations. This yields a system of three linear equations with three unknowns
\[ v_2 = 0 \, , \] \[ v_1 + v_3 = 0 \, , \] \[ v_2 = 0 \, . \]These equations are linearly dependent. We immediately see that \(v_2 = 0\). Let us choose \(v_1 = 1\) and therefore \(v_3 = -1\). This determines the direction of the eigenvector corresponding to the eigenvalue \(0\). We now normalise it
\[ \frac{1}{\sqrt{|v_1|^2 + |v_2|^2 + |v_3|^2}} \begin{pmatrix} v_1 \\ v_2 \\ v_3 \end{pmatrix} = \frac{1}{\sqrt{1 + 0 + 1}} \begin{pmatrix} 1 \\ 0 \\ 1 \end{pmatrix} = \frac{1}{\sqrt2} \begin{pmatrix} 1 \\ 0 \\ 1 \end{pmatrix} \, . \]Thus, we have obtained the normalised eigenvector of the matrix \(\hat L_x\) corresponding to the eigenvalue \(0\)
\[ \vec v = \frac{1}{\sqrt2} \begin{pmatrix} 1 \\ 0 \\ 1 \end{pmatrix} \, . \]When determining the eigenvector \(\vec w\) corresponding to the eigenvalue \(-\hbar\), we proceed in a completely analogous way
\[ \left ( \hat L_x - \lambda \hat{\mathbb{E}} \right ) \cdot \vec w = \left ( \frac{\hbar}{\sqrt2} \begin{pmatrix} 0 & 1 & 0 \\ 1 & 0 & 1 \\ 0 & 1 & 0 \end{pmatrix} + \hbar \begin{pmatrix} 1 & 0 & 0 \\ 0 & 1 & 0 \\ 0 & 0 & 1 \end{pmatrix} \right ) \begin{pmatrix} w_1 \\ w_2 \\ w_3 \end{pmatrix} = \] \[ = \frac{\hbar}{\sqrt2} \begin{pmatrix} \sqrt2 & 1 & 0 \\ 1 & \sqrt2 & 1 \\ 0 & 1 & \sqrt2 \end{pmatrix} \begin{pmatrix} w_1 \\ w_2 \\ w_3 \end{pmatrix} = \begin{pmatrix} 0 \\ 0 \\ 0 \end{pmatrix} \, . \]We divide this equality by the factor \(\frac{\hbar}{\sqrt2}\) and expand it into its component equations. This yields a system of three linear equations with three unknowns
\[ \sqrt2 w_1 + w_2 = 0 \, , \] \[ w_1 + \sqrt2 w_2 + w_3 = 0 \, , \] \[ w_2 + \sqrt2 w_3 = 0 \, . \]These equations are linearly dependent. According to the established convention, let us choose \(w_3 = -1\). From the third equation we then obtain \(w_2 = \sqrt2\), and from the first equation \(w_1 = -1\). This determines the direction of the eigenvector corresponding to the eigenvalue \(-\hbar\). We now normalise it
\[ \frac{1}{\sqrt{|w_1|^2 + |w_2|^2 + |w_3|^2}} \begin{pmatrix} w_1 \\ w_2 \\ w_3 \end{pmatrix} = \frac{1}{\sqrt{1 + 2 + 1}} \begin{pmatrix} -1 \\ \sqrt2 \\ -1 \end{pmatrix} = -\frac{1}{2} \begin{pmatrix} 1 \\ -\sqrt2 \\ 1 \end{pmatrix} \, . \]Thus, we have obtained the normalised eigenvector of the matrix \(\hat L_x\) corresponding to the eigenvalue \(-\hbar\)
\[ \vec w = -\frac{1}{2} \begin{pmatrix} 1 \\ -\sqrt2 \\ 1 \end{pmatrix} \, . \]



